Computationally Based Measures of Amine Azide Basicity and Their Correlation With Hypergolic Ignition Delays
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Computationally Based Design and Screening of Hypergolic Multiamines
Seeking to identify structural features of saturated, (all) tertiary, alkyl multiamines (STAMs) that correlate with hypergolic ignition delays, conformers of STAMS whose ignition delays have been measured were established through density functional theory-based calculations. Examined from the standpoint of lone pair/(C-N and C-C) bond orientations, a correlation is suggested. Conformers of 1,3-...
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Complexation of amines with borane converts them to hypergols or decreases their ignition delays (IDs) multifold (with white fuming nitric acid as the oxidant). With consistently low IDs, amine-boranes represent a class of compounds that can be promising alternatives to toxic hydrazine and its derivatives as propellants. A structure-hypergolicity relationship study reveals the necessary feature...
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Liquid propulsion systems have effective role in implementation of space and military mission due to high performance and specific impulse. Liquid propellants are divided into two categories: hypergolic and non-hypergolic propellants. Non-hypergolic propellants need an igniter system to provide the initial energy for propellant ignition compared with hypergolic propellants. Since failure in ign...
متن کاملFourier transform infrared studies in hypergolic ignition of ionic liquids.
A class of room-temperature ionic liquids (RTILs) that exhibit hypergolic activity toward fuming nitric acid is reported. Fast ignition of dicyanamide ionic liquids when mixed with nitric acid is contrasted with the reactivity of the ionic liquid azides, which show high reactivity with nitric acid, but do not ignite. The reactivity of other potential salt fuels is assessed here. Rapid-scan, Fou...
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A hypergolic bipropellant s consist of fuels and oxidizers that can ignite rapidly upon mixing without external ignition devices . This self –ignition technology makes the engine ignition more reliable with repeated use. Recently, ionic liquids with the dicyanamide anion which shown good hypergolic properties when contacted with common oxidizer such as concentrated nitric acid, were attracte...
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